Well I have finally sorted out some of the issues of this marriage and received their marriage certificate. It is indeed the correct coupling. The Cert. shows that William was preeviously married to Maude Okker, his age 45, Alice 40 and a Spinster, her father named William, occupation Butler.
I have also found 1901 Census, where she was living with her mother Eliza (49). Alice was born in Marylebone, London, and living in South-West Hackney. In 1911 she was living alone (30) at 10 Birkbeck Road, Dalston, South-West Hackney, occupation was Restaurant Cook.
What I am really chasing now is her ancestors starting with her parents William & Eliza but having trouble trying to find the right ones, as it appears her mother died between 1901 & 1911, and her father was shown as deceased on her Marriage Cert., and he wasn't on either of the Census sheets.
Hope someone can help or point in the right direction.