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First of all there was a large branch or several branches of Hopkins in and around Clonegal.
Nicholas Hopkins (c1723-1787) married a Sarah Brown and they had a daughter Susannah, probably around 1770
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Re your Susannah Hopkins, c1809, of Clonegal. I believe she was a daughter of another Susannah (c1773-1844), likely the daughter of Nich and Sarah, above. Susannah married a William Hopkins (c1768-1809). This family lived at or near Clonegal in Carlow and were said to be 2nd cousins. William, the father left his daughter Susannah 60 pounds in his will to be invested for her. Some old handwritten notes about the family only mention 6 children...leaving out a Sarah who died young, and this Susanna. I therefore believe that Susanna also died young and is thus not the Susan who married John Langrell.
Can you explain your source for saying that "Susan", wife of Langrell, was born at Clonegal in about 1809 and also regarding her death in 1860?