I am searching for anything and everything on anyone
It's better for everyone if your a bit more specific in what your asking for as you will get information you might already have & you will also get information about various members & branches of the family which will get very complicated.
Do you have his marriage cert?
I'm assuming he's this one:
1861
Charles Humphreys 30 PC Newport Salop.
Hannah Humphreys 28
Thomas Humphreys 7
Martha Humphreys 4
Frances Humphreys 1
Amelia Williams 56
John Williams 16
RG9; Piece: 4010; Folio: 5; Page: 3
Probably him in 1841;
Edgmond (2mls. from Newport)
Dorothy Hample 43
Charles Hample 11
Mary Hample 8
Fanny Hample 6
James Hample 4
Mistranscribed as Hample.
HO107; Piece: 905; Enumeration District: 10; Folio: 7; Page: 10
I can't see a Baptism for Charles but I believe these are his siblings;
Joseph Humphreys ch: 5 June 1822 LONGFORD BY NEWPORT
Sarah Humphreys ch: 22 February 1824 NEWPORT
William Humphreys ch: 6 November 1825 CHURCH ASTON
Elizabeth Humphreys ch: 11 November 1827 CHURCH ASTON
Mary Humphreys ch: 25 September 1831 CHURCH ASTON
Frances Humphreys ch: 9 February 1834 CHURCH ASTON
James Humphreys ch: 18 October 1835 CHURCH ASTON
father: James Humphreys
mother: Dorothy
James Humphreys married Dorothy Penson 1822 Longford Salop.
1851 has this:
Dorothy Humphreys 54
Mary Penson 6 neice
Which confirms it.
HO107; Piece: 1998; Folio: 200; Page: 10
Dorothy:
Dorothy Penson ch: 1798 LONGFORD BY NEWPORT
father: Andrew Penson
mother: Mary
Edit:
FindMyPast has a Charles Humphreys Bapt. 1829 Church Aston.