It looks likely she had a brother James Toleman, a tailor like his father, who married also at Christ Church Newgate St in 1832, to Mary Ann Charlotte Millward.
1841 census
Tabernacle Walk, St Luke, London & Middlesex
James Tolman 1796 occ Tailor
Mary Tolman 1801 Middlesex, England
Mary Tolman 1826 Middlesex, England
John Tolman 1836 Middlesex, England
Frederick Tolman 1836 Middlesex, England
James Wm Tolman 1841 Middlesex, England
Elizabeth Tolman 1839 Middlesex, England
Thomas Millward 1836 Middlesex, England
James Snr . not born in this county
John Toleman
Baptism 22 Sep 1833
Baptism Shoreditch St Leonard, Hackney
Father: James Toleman occ Tailor
Mother: Mary Ann Charlotte
Abode Tabernacle Walk
Frederick Tolman
Baptism : 28 Sep 1834
Baptism Shoreditch St Leonard, Hackney,
Father: James Tolman occ Tailor
Mother: Mary Ann Charlotte
Abode Tabernacle Walk
James William Toleman
Baptism 2 May 1841
Baptism Place: Shoreditch St Leonard, Hackney
Father: James Toleman occ Tailor
Mother: Mary
Abode Tabernacle Walk