Thank you so much for responding.
According to his death record in Australia 1884, Valentin was about 81.
His parents were married 17 Feb 1795 in Honningen, Adenau, Rheinprovinz, Preuben, Deutschland.
Brother Andreas born 22/5/1795 Waldbreitbach, Rheinland, Preuben
Sister Christina born 15/9/1796 " "
" Anna Catharina born 21/10/1797 Siegen, Westfalen, Preuben
Brother Joannes bap 31/12/1801 Koblenz, Rheinprovinz, Preuben
And a huge thanks for the original marriage details for Valentin. I can't read it, but that's okay.