I think the percentages the two of us are referring to might be two different things? Yours seem to be saying the percentage of probability of X relationship. The percentages I am talking about is the total percentage of DNA that we share.
The only certainty in percentages of DNA shared is between parents and their children. All other relationships are variable, to the extents indicated by the DNA Painter tool and similar charts. You also have to beware of outliers - individuals who might share a substantially higher or lower percentage of DNA than the normal range for any given relationship.
DNA Painter expressed the probability of particular relationships for the percentage or amount of DNA shared between individuals. It is a handy tool, but it is important to recognise that just because a certain relationship has the highest probability, it doesn't follow that it is necessarily the correct relationship for your circumstances.
You have to do the traditional research, look at the probabilities of relationships between individuals you have researched being related in various ways, and compare those relationships with the probabilities suggested by tools such as DNA Painter. Nothing is certain, and trying to establish a specific relationship purely by the amount of DNA shared is fraught with difficulty.
I can give a couple of personal examples. My brother has a relatively low share of 59 cM with a 2nd cousin.
We have three 2C1Rs, all siblings born of the same parents. My shared matches with them range from 23 cM to 147 cM.