Form number is the number of the census form. See the first link above.
The forms are all standard, the same form is used in urban (where they are likely to have house numbers) and rural (where they are very unlikely to have house numbers) so rural houses are given the number of the form to make doing the census easier.
I lived on a Main Street of a small town and no house ever had a number until eircodes were introduced a few years ago.