According to Ancestry, Samuel must have married Hannah before 1827
England, Select Births and Christenings
George SKUSE
baptism date: 15 Jul 1821
baptism place: Bristol, Gloucester, England
father: Samuel SKUSE
Mother: Hannah
Bristol, England, Select Church of England Parish Registers
George SKUSE
Male
Single
Marriage date: 31 Jan 1841
Marriage Place: Bedminster, St John, Somersetshire, England
father: Samuel SKUSE
Spouse: Louisa PULIN
You will find Louisa SCUTE (as spelt on Ancestry) - living with (along with others) a Fanny PULLEN aged 22 and John PULLEN aged 14 on the 1841 census, at St Philip & St Jacob
1861 Census
St Philip & St Jacob
SKUSE
George - 40 - Labourer, born St George, Gloucester
Louisa - 40 - all born St Philip, Bristol
Aaron - 17 - labourer
George - 14 - cotton spinner
Abraham - 12
Samuel - 8
Emily - 8
Daniel - 1
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Hannah/calls herself Ann (SKUSE) aged 69 on 1861 census, (=c1785) says she was born in Fishponds, Gloucestershire.
Looking at the 1851 census, Fishponds is in the Parish of Stapleton (district 2d) - and only covers under 3 pages of the 14 in total.
On the 1841 Census, Fishponds is under, Stapleton, District 3 - and Fishponds only covers two sides
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Family Search does have a baptisms at Stapleton, Holy Trinity
Female SKUSE, 4 April 1813 - parents: Samuel & Ann
and
- 23 December 1815
female SKUSE, father: Samuel and mother ANN (could well be Hannah, as she does call herself Ann on the 1861 census)