Hi
Short answer is I have no idea.
Longer one is that I did a web search and came up with this
http://www.childrenshomes.org.uk/LiverpoolStEdward/That says the orphanage was in Thingwall Road, Broadgreen, from 1903 and was run by the Brothers of Charity.
The College was, as far as I can tell, originally in St Domingo Rd, Everton and then in Sandfield park, West Derby and was run by the Christian Brothers.
I don't have enough knowledge to know if the Christian Brothers and the Brothers of Charity were two different orders, but I suspect they were.
If you or your friend have further questions perhaps posting on the main Lancs board could produce more info than I have. Not too sure this (resources) is the right board to discuss it but have no idea how to move the topic :-)
Boo